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nickle cadmium edison batteries | 5 comments (5 topical, editorial)
Re: nickle cadmium edison batteries (3.00 / 0) (#2)
by clflyguy (sidney.raiford@gmail.com) on Wed Jan 9th, 2008 at 08:32:54 AM MST
(User Info)

RR, 30% is the number you're looking for. Some janitorial supply places sell KOH
in a 45% liquid form, dilute as necessary. Rinse them out with distilled water, then
fill with electrolyte to the fill point, this varies on different models of cell.
Pour about 5/8" of pure mineral oil on top of the electrolyte immediately after
filling. This keeps atmospheric CO2 from ruining the electrolyte. Charge and heavily
discharge them 5 or 6 times, while observing their cycling ability. Now charge and
let sit for 2 weeks no load. If you have the nominal 6v/5 cell@1.2v per cell wood
crate style like mine then your cells can actually go as high as 1.7v per cell.
After 2 weeks sitting untouched, choose the cells that still show at least 1.0v per
cell. Pull these out to make new batteries from. Among the cells that you save, try
to match as closely as possible the individual cell voltages for each new battery.
In my conversations with a rep at Nife, he told me that you can usually revitalize
old flooded cell nicads with this procedure. If it doesn't work, then they are well
and truly shot. Battery recyclers love old nicads- they get more for them.  -Gus



Re: nickle cadmium edison batteries (3.00 / 0) (#4)
by stasis on Mon Jan 14th, 2008 at 06:17:27 PM MST
(User Info)

Here's a little bit more on recycling nicads at home in your spare time.

Whatever the percentage of flake KOH to distilled - or reverse osmosis filtered with a de-ionizing cartridge chaser - water, the goal is to reach a specific gravity of 1.19 to 1.22 at 60 deg. F.  The higher s.g. is for very cold weather, the lower - normal - for greater cycle life. Patterson's article in HP #15 covers this and more.

Here are some nominal figures for S.G   @   Deg. F:
                                  1.182     90
                                  1.185     80
                                  1.187     70
                                  1.190     60
                                  1.192     50

About 0.01 of S.G decrease per 4 deg.F temp. increase.  Another "Gotcha" is the state of charge and the electrolyte level in the cell; check out the HP article.

Chevron utility oil 22 can be hard to find in less than 55 gal. drum lots.  Y'r local friendly distributor can tell you what they can come up with.  The critical factor here is that the oil is what's called a "Wax Free" oil.  The likeliest source I've found so far is an old fashioned (?) meat locker refrigeration plant, they use the wax free oil as lube for their compressors, and get their oil in five gallon pails, sometimes.  Talk to the guy who maintains the machinery, may be willing to part with a gallon or so for $20; good to bring your own container. The "22" designation refers to the viscosity, and I wasn't able to find that, but did get a heavier viscosity of utility oil "68".  It seems to be working. . . .

The oil layer should be 1/8 inch to 3/16 inch thick; about 4 millimeters.

On calibrating the hydrometer, I can't find my notes; they were just a bunch of arithmetic anyway, and if you google sodium chloride and specific gravity you should come up with the same stuff I did.  Since I was aiming for 1.20 for my S.G. and the salt trick, as I vaguely remember gave me a figure of 1.2004 to calibrate to, it was a pretty good fit, but check it out for yourself.
Hope this helps, take care,

[ Parent ]



nickle cadmium edison batteries | 5 comments (5 topical, 0 editorial)

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