Polyester doesn't stick to anything. Vinyl is virtually an epoxy and will need to be treated much as you would an epoxy. Decent mould preparation and proper release techniques will be needed.
I personally would hesitate to use wood as a mould, it will require a lot of filler, sanding and preparation. I think Dan has gone to some plastic stuff and for good reason.
Maybe the candle wax treatment or something will get you a release from wood. Someone suggested PTFE film and that will release it. Even silicone coated mylar will probably do, but I am not sure of its availability, we used it on epoxy coil formers. Definitely I would consider petroleum jelly a no go even on well polished metal moulds.
I haven't had experience of vinyl ester but releasing epoxy can be a real pig and it seems as though the basis of vinyl is the same as epoxy so treat it accordingly even if it is less problematic.
Flux
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