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What happens if battery is overcharged until "dry"


By Ungrounded Lightning Rod, Section Homebrewed Electricity
Posted on Sun Oct 10, 2004 at 02:05:29 PM MST
If a flooded lead-acid is overcharged slowly until the plates uncover, what happens?

I have a sailboat with a combo starting/deep cycle battery and a solar panel to keep the battery from going flat when the boat isn't used for long periods.

Unfortunately, the regulator doesn't keep the panel from putting enough voltage into the battery to electrolyze the electrolyte away.  The battery is in a horribly inconvenient place to check the level, and over the several years since I last replaced it the battery has, on two occasions, been electrolyzed down to below the level where it will start the engine.

Attempting to start the engine in this condition apparently causes the formation of bubbles on the remaining wetted surface which suddenly "disconnect" the battery under the heavy load, then bubble away a few seconds after the load is removed.  Lower level loads (like lights) shut down during cranking, come back when cranking is stopped, then suddenly brighten up a couple seconds later.  (No, there's no circuit breakers or other electronics to explain this, and the delay varies.)

On both occasions I've refilled the battery with distilled water.  When first done the behavior is the same, but after an hour or so (I'm guessing: once the plates are well wetted and the acid and water are mixed better) it is able to crank the engine nicely, even if this is after dark and no charging has been done.  When I went back after a week or so the battery seemed fine, capable of many minutes of cranking (in half-minute bursts, of course).

My question is:  What happens to such batteries when they are electrolyzed down to such a low level?  What sort of damage, if any, should I expect?  Is the battery likely to be OK at this point, have resuced capacity, or perhaps be prone to some sort of sudden failure?

What happens if battery is overcharged until "dry" | 3 comments (3 topical)

Re: What happens (3.00 / 0) (#1)
by JeroenH on Mon Oct 11, 2004 at 08:59:10 AM MST

Sounds like your charge controller is not, uh, controlling the charge :-)

Seriously: a good charge controller should keep a L/A battery in good shape for long periods of time. Seems to my like your charge controller is not reducing the current as the battery approaches the 100% full state.



overcharged until "dry" (3.00 / 0) (#2)
by troy on Mon Oct 11, 2004 at 01:04:08 PM MST

Exposed dry plates is your battery's way of saying goodbye.  Now when exactly it will fail completely is still an open question.  If it was only dry for a "little while" that's of course better than bone dry for a month.  Normally, once they get dried out, both lifespan and reserve capacity suffer badly.  The one possible exception to this is that some batteries use glass mats to wrap the plates with, wicking electrolyte up to the exposed portion, but I doubt you have that type.

YMMV

Good luck and have fun,

troy



Re: What (3.00 / 0) (#3)
by ghurd on Tue Oct 12, 2004 at 08:23:01 AM MST

Strange bubbling is a sign the battery is about done.

Also- A PWM controller uses less water. And one with a 'sealed' battery setting (lower V) could also help... I think.

G-



What happens if battery is overcharged until "dry" | 3 comments (3 topical)
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