A plug in hybrid has an active rectifier, as per 5% harmonics requirement.
A normal hybrid has an active rectifier on the generator side, and an inverter on the motor side. You can't tie into these, without reprogramming the controller, something that would take a few experienced engineers a few weeks to do, but could be done.
The dc link is 120, 220, 240, 260, 320.. volts, depending on the car.
A few cars had a voltage doubler, and used a ~250 volt battery on a 500 volt motor, this allowed for a 100KW motor, on a "safe" battery voltage.
For simplicity, you are going to need a 200+ volt system and a converter for charging the battery directly.
Running a plug in hybrid off a modified sine wave inverter is not an efficient solution.