I'm using PVC blades too.
The last set I made, I drilled the mounting holes first and made them 2 inches longer than I needed them. I put all the blanks together and then drilled a hole at the tip in the excess bit. I could then fasten all the blade blanks together with these holes and cut them all at the same time. This means that they have the same shape.
I then use the holes, root and tip, to fasten the blades to a piece of wood that I can hold in the vice. This makes shaping the trailing edge much easier. When the blade are nearly finished, I cut the excess tips off.
It isn't perfect though, because the blades can't fit into each other well as they all have the same radius, but it does help.
I also use the craftknife-blade-as-a-scraper technique mentioned above, and I found it gives a really good finish.
One thing I have noticed though, is that however carefully I make the blades to the same shape, they have different weights. I think this is due to the pipe not being uniform thickness to start with. I've ended up with 10g between the lightest to heaviest blades.