Hi Mikey,
Sounds like we both have similar systems. I built my woodstove/water heater (not boiler) out of 3/8 plate steel, lined completely with water jacket and plumbed to 500 gal stainless water tanks in basement. Anyway, my chimney flu is lined with 6", 10ga (.109' thick) tube we use at work for meteorological (wind measuring) towers.
Coming out of the firebox is 8" dia, gradually reduced to the 6" over 30" (cone shaped part) inside that cone I put a welded up heat exchanger "box" with fins on the outside. It's plumbed in series with the water jacket. So I'm sucking some of the flu heat into the water. Now, on the outside of the 8" to 6" reducer, I jacketed it completely, but not for water heating, but for AIR heating. I force cold air up through it and exit the hot air via aluminum dryer hose to a duct in our living room. The air comes out typ. at 180-200F. and can maintain our little 900 sq ft ranch here in Vermont at 65-66 when it's 20 outside. If more heat is need, we turn on the basement blower, through a truck radiator and use the water stored heat. It has been working well for over 3 yrs now and my next system is currently underway.
Anyway, creosote has not been a problem. Once a month, I go on the roof and run a brush down the tube once, and it looks like a gun barrel. I've been burning mostly pine and cottonwood (free).
Anyway, like to hear more about your system
take care,
Bret