I think the easier way would be to leave the tank's unpressurized, circulate water through PEX tubing between the boiler and the tanks, putting, I don't know, 15 feet in each drum. In the drum, add an anti-corrosion agent, and perhaps top each drum with 1/8" of mineral oil. This will keep oxygen out of the water, reduce corrosion, and keep the water from evaporating.
If you want to keep the water hotter, dissolve salt or calcium carbide in the water. This will also make it more corrosive.
The circulating water will have fairly small volume, so you can pressurize it reasonably safely, and/or add material to raise it's boiling point.
Check the specs on the PEX tubing.
For distributing the heat, build a styrofoam box around the barrels, and put a shuttered fan at one end, and a shutter at the other.
Quantities:
A barrel of water is nominally 55 gallons. at 8 lbs/gallon that's 440 lbs.
If you raise the temp to 180 degrees, you'll have about 100 degrees to work with.
So a barrel will hold about 44000 BTU.
If you have a 20 x 40 foot shop with 10 foot ceilings, you have 1200 square feet of wall and 800 sq feet of ceiling. 6 inch walls are R20, 12 inch ceiling is R40.
So the walls leak 60 BTU/F The ceiling leaks 20 BTU/F So 80 BTU takes care of the wooden part.
10 x 10 shop door 2" thick styrofoam filled = R5. That's another 20 BTU/F/Hr
3 x 7 people door 2" thick styrofoam is another 4.
10% wall used by window = 120 square feet at R2 (typical double pane) = 60 BTU/F/Hr
So that's 164 BTU/F/Hr
Round UP. 200 BTU/F/Hr. Now Rule of thumb. You'll use this much again heating air exchange. Probably more when you're working, less when you're on coffee. 400 BTU/F/Hr.
It's -30 outside. It's 70 inside. So we're back to 40,000 BTU/ hour -- That's the extreme case. So a barrel of hot water holds an hour of heat in bitter winter weather.
Lets' loosen up a bit:
You want the shop to stay above freezing when you aren't in it. Differential temp is now only 60 degrees, and if your detailing is any good, you're a lot closer to 200 than 400. Under these conditions, 1 barrel is heat for 3 hours.
So: 8 barrels would let you get away with one firing a day.
If your temps are never that cold, adjust accordingly.
One other thing: Put a big truck radiator from the local wrecking yard in the loop.
Put the fan so it blows through it on the way OUT of the box. But the water goes through the radiator on the way INTO the box. Now you come in in the morning, the shop is cold. Turn up the thermostat. Fan comes on. As soon as there is hot water in the radiator, your shop starts warming up. When the shop is warm enough, the fan shuts off, and most of the heat goes to heating the barrels.