I don't know your machine well enough to tell you how to adjust the field. If it is wound field then it would have a rheostat. Some of those are permanent magnet and if you have a key it is probably used to alter the air gap or a magnetic shunt.
The idea of altering the field is to get the turbine running at optimum speed where it produced maximum power out. This would mean setting the field so that it runs on load at something like half its no load speed. You could just tweak it for maximum current.
I would imagine that fitting a second nozzle would be fairly straightforward. You would just copy the mounting of the original one and aim it as for the original. You may have to f drill the casing as you suggest. You will need a manifold to feed both nozzles with the full flow available, the restriction ( and speed increase) must come from the nozzle itself.
I would expect someone here to know about how your key changes the field but if you can give a link to the details you have I may be able to sort it out.
Flux