I am not clear on the wheel and motor relationship.
You want to drive a stepper motor from the rim? Or the motor is connected to the wheel hub?
Most steppers don't need to turn very fast to get up to charging voltage for AAs.
Driving it with the rim is going to get the motor turning a lot faster than it needs to turn.
Steppers tend to peak out on the output at a fairly low speed. Much faster motor RPM than the peak output gains nothing, and a lot faster may even hurt.
I'm not sure how large the steppers are, but hanging a bike wheel directly on the shaft can't be a good idea. Maybe connect the bike wheel to a jack shaft, then connect the motor at the other end of the jack shaft?
Sometimes, a large stepper connected to the right amount of thin metal (blades?) can resonate due to the cogging, and very loud. Creepy too, like 100 out-of-tune hillbilly hand saw instruments.
G-