Hi Dave,
!! Nice workmanship !!
I still don't understand exactly how the collector is plumbed into your homes hot water system? Is the collector a "batch" style collector, in which the hot water storage is the collector itself, and the cold water only makes one pass through the collector, or is there a pump that pumps water through the collector to a hot water storage tank?
This makes a difference, in that if its a batch collector, you have a very high ratio of glass area to water storage area -- about 32 sqft of glass for 8.5 gallons of water in the collector, or about 3.5 sqft of glass per gallon of water. The usual would more like half a sqft of glass per gallon of water. So, if its a batch collector, then with the large amount of glazing per gallon of water, I think it hardly matters whether you paint the insulation or not -- the water is going to get quite hot either way. This is especially true with your high ambient temperatures.
If its a collector that you are pumping water through all the time, and you want to maximize the heat transfer to the copper pipes, I'm not sure which scheme (paint or no paint) would work best. With no paint, you will lose some heat because some incoming sun will get reflected back out the glazing. With paint, the box air temperature will be high, and you will lose heat out the glazing by convection/conduction.
The usual way to get the heat from sun that does not direcly strike the pipes into the pipes would be to have fins that are thermally bonded (eg soldered) to the pipes, and that extend half way to the next pipe. This is a good arrangement in that the heat from the sun that strikes the fins gets conducted directly into the pipes. You could still do this on yours by attaching aluminum or copper strips to the pipes above the insulation. The better the bond you could provide from the fins to the pipe the better it would work. These fins would also protect your insulation from direct sun exposure. One way to attach such fins to copper pipe is to use a collection of boards to make a groove that is just a touch wider than the pipe and half as deep. Then place the light aluminium or copper fin material over the groove, and using a piece of the copper pipe and a mallet, pound the pipe into the groove. This forms the fin material into a half circle that fits the copper pipe. Then put some silicone between the copper pipe and fin, and clamp them togehter until the silicone sets. This is not as good a solder, but (I'm told) works pretty well. Its similar to this scheme: http://www.builditsolar.com/Experimental/CPVCCollector/jig.htm
Another possibility that might work is to use a trough type reflector behind each tube. The best type of reflector would be whats called a non-imaging reflector -- these will reflect heat onto the pipe for a wide range of sun anlges so that you don't have to track the collector on the sun as would be required for a parbolic reflector. This sounds like more work than it is (I think :-)) the reflector contours would not be critical, and you could make a would tool to shape the troughs. It would be an interesting experiment. If you are interested in this, I can probably help you determine a good shape for the trough relfector -- let me know.
I am assuming that the 4 pieces of glazing go side by side, not one on top the other?
Gary