Ogou;
I do something similar for our chest style freezer. The UPS is rather small and I modifed the side panel where the battery is by putting battery lugs on it to connect the external batteries. This way I can take them off and recharge them or use them else where when I need to.
One of this things you'll find is that at anything more then 3 times the current internal battery rating and the internal charger will have problems keeping it charged. You'll actually be able to hear it kick in and out as it constantly tries to charge it up if gets gotten too low due to power outage or something.
The top of the UPS will indeed get hot to the touch, which is due to over driving the battery charger.
With respect to the usage of the larger battery sets. I have not had any problems connecting 7 external SLA together during our past power outage. Make sure to use high quality mulit-strand wire connections and you will be just fine. After our power was back on, I disconnected my externals and put them on the solar charger.
You will need to be sure and not allow the UPS charging circuit to charge through the solar panel:-) but I'm sure you've already thought of this.
What uses do you have in mind for this unit.
To let you know, mine isn't setup the be able to start the Freezer, just keep it running . I have found that while the mains is on the freezer doesn't have any problems starting while on the UPS, and will keep running when I give it a false outage ( unplugged from mains)with no probelms , this included listening to it start the compressor and such.
If it for something else such as lighting then you shouldn't have any problems.
We even had TV on another similar UPS for several hours each day, by merely having the internal battery stay healty by switching out external batteries.
Let us know what your plans are, there are several who went through the Midwest outages that can give real-life accounts.
Above all HAVE FUN!!
Bruce S