I think he's talking about making a flat spot for mounting the magnet, rather than welding the magnet itslef. Yes, you can build up a flat spot by welding some metal on then grinding it flat.
Don't heat the magnets - even momentarily. Even if you don't light them off, once they get above their "curie temperature" the suddenly become completely demagnetized - and don't get it back when they cool off.
A very large wheel with a lot of magnets cutting a lot of coils is an excelent way (indeed, the classic way) to generate from a high-torque, low-speed shaft. This is exactly what is done in the large machines used in, for instance, hydroelectric dams.
The large radius acts as a lever arm, trading force for speed just like a gearbox (but without the friction and wear).
The large number of poles takes advantage of the speed by providing a large number of edges where flux cuts conductor - incidentally raising the frequency. This is like having a large number of generators attached to the "output shaft" of your "gearbox", alowing you to make each generator smaller, compensating for the increased number of magnets by reducing the size of each. This might mitigate the increased cost for the larger number of magnets.
The main thing you need to deal with, if you build your genny on one of these wheels (assuming you can't get two of them adjacent for an axial flux design or two rims concentric for a concentric-dual-rotor radial flux design, is designing a flux return path that doesn't consume a bunch of your energy in eddy currents. For an axial-flux machine a spiral of metal strip will serve. For a radial flux machine a slinky-like wound strip, or a stack of thin disks like enormous washers, will do the job.