Russ: It will charge your 24v bank of batteries and it may preform as an extra low wind machine. However as mentioned above it may have a hard time starting in the wind. You'll just have to try it out.
The prop has to achieve a certain speed before it starts absorbing the entire wind energy available in the disk area. If it runs too slow, it can't come up to the proper tip speed.
4kw \ 120v = 33.3 amps so if you charge into a 24v battery bank, at best you will only be able to charge 33.3 amps or about 1/5th what you could do if you were to buy 3 transformers (if your wind plant is 3 phase) and step your current / voltage ratio down properly. Unless you use transformers to step it down you are making use of only 20% of your wind generators capabilities.
But it shouldn't harm it if you want to try running it as you suggested.
John II