The "theoretical optimum" angle would be lined up with the sum of the force vectors.
In practice, pointing the anchor just a "tad" below the angle of the top guy is close enough. The load on the top guy wire in a storm is much higher than the sum of the pre-tension and wind loads on the lower guy wires. If you went to the trouble of measuring all of the loads, or at least calculating them with a finite-element model, you could find out how big the "tad" would be for that tower.
As a guess, a 4" pipe tower is so flexible that the top guy rules (line up the anchor with it and you're done), while a heavy truss tower has so much cross-section drag and stiffness, that the intermediate guy wires would have more effect (so tilt the anchor down some).
Don't forget that you will put pre-tension on the cables (they should never go slack, even the back cables in a strong wind) so your pre-tension will straighten the anchor some, too, and give you a hint about the angle they really want to take up.
Information that would only be useful if you were to build that tower again, mind you...