You could do it with a rotary converter - a free-spinning motor with both three-phase and five-phase windings.
Start with a motor rated for at least twice the horsepower you'd get from your mill if it were spinning at a speed to produce the motor's rated frequency (and ignore the fact that running it that way would fry your genny in minutes - you're just sizing the motor's laminations and windings). Tear out the existing windings and count the turns. Rewind it with half the copper allocated for the three-phase winding, half for the five phase winding. To compute the size of the three phase winding again assume the genny is spinning to produce the motor's rated frequency and compute the under-load voltage. Start by assuming the same number of turns in the motor but with a wire of half the cross-section, then multiply the turns by the ratio of your genny's output voltage to the motor's rated voltage and resize the wire to divide the cross-section by the same ratio, ending up with the same total cross-section of wire for the three phase winding. The five-phase winding also has that cross-section so you'll need another factor of 3/5ths for that winding's wire size.
Your slot count will probably come out wrong so you'll have to wind some of your five-phase windnigs with turns distributed between adjacent slots so the composite pole comes out in the right place - and you may get an efficiency hit from this.
(You can get a similar effect by appropriately winding and interconnecting transformers. But without the mass of the motor's rotor to transfer energy between phases you end up with voltage droop if your three-phase load isn't phase-balanced).
But why in the world would you want to do this?
If you're trying to run a motor it will still change speed and power as the wind changes and the mill speeds and slows. AC appliances don't like lower than rated frequencies. Resistive heaters (including incandescent lights) don't care about waveform and frequency - just RMS voltages and currents. And if you're rectifying it to charge batteries or the like, five-phase is better than three-phase for charging smoothly.
Meanwhile, any conversion is going to drop a nontrivial percentage of your power as heat in the converter.