I see no reason why blades made out of PVC will not work. You already have experience shaping it, so it should be easy for you to do.
The main drawback that I see is that the brittle temperature of PVC -5F (-15 C). Another thing is that PVC is not UV resistant, but that can be remedied with a good coating.
You can put a piece of steel electrical conduit inside to give it strength. That material is light, strong and cheap.
It would be good to be able to find alternate ways for DIY's to build blades.
By the way, tell your girl to put on some boots before she goes in the woods to hunt for elk
Ed