Thanks Flux!
We're only generally talking about a max of ~6A at 12V, and more usually nearer 2A.
That 6A is when I'm effectively dumping excess with my software dump load!
It's difficult to measure the voltage at the battery and at the converter at the same time as they are on different floors, but the LVD (my home-brew design, see http://www.earth.org.uk/low-voltage-drop-out-circuit-design.html ) is inches upstream the DC-to-DC converter and it did oscillate much much worse (basically for every 'on' transition) before I added the cap, since the converter takes a huge slug of energy to start up I think. Note also that demand from the laptop seems remarkably spiky, especially while it charges its internal battery. I can't reasonably get the battery physically any closer to the load, and I didn't leave much slack in the wiring as is.
After my next planned 10x expansion in battery (if it comes to pass), the batteries will drift yet further from the load unless I can get the Li-chemistry ones, as there is not space to accommodate 400Ah of SLA in the house safely...
(The LVD is set up to come on somewhere over 13V and drop out a little over 12V, BTW.)
But yes, it is interesting to see in practice how valuable the extra copper is. I shall continue to mentally oversize the wiring from now on with a "double it, and again..." approach!
Rgds
Damon