Hmmm... interesting thought.
If you used curved (or fauceted) glass, you would need to have a large air gap under the glass, and the glass would have to extend far beyond the edges of your panel.
With the mirrors and odd glass shapes, you are quickly approaching the subject of using mirrors and prisms to effectively increase the surface area of your panel.
For example, take your basic 6 foot satellite dish and mirror the inside, then point it at the sun. It should focus a very intense beam about where the satellite reseiver should be. However... most "ordinary" solar cells wouldn't be able to tolerate that kind of treatment for long.
A solar oven does about the same thing.
Remember that for solar panels, heat is an unwanted byproduct.
Oh...
I was just thinking.... it might be worth looking up some of the research on diamonds. If I remember right, the faucets on diamonds are generally designed so that wherever ambient light enters a diamond, it is reflected back up through the top faucet, thus adding to the brilliance of the stone. And... even light bouncing down through the top faucet tends to reflect back up through it...
The effect has to do with the angles that the light hits the faucets and whether the light is reflected internally or passes through the faucet.
Anybody have a cheap 10,000 ct clear diamonds available?