Watts stays constant.
Watts = Voltage X Amperage
So as voltage goes down, amperage must go up and vice-versa.
Volvofarmer's bit about the 1KW of solar would be to compensate for the fact that your boss would be using his air pump for 8 hours at 500W, or 4KW/Hrs. Daytime sunlight is generally only good for about 4-5 hours, so to make up for any clouds, etc he suggested 1KW worth of solar which would equal your 4KW/Hrs.
And since you generally only want to run batteries down to no less than 50% before charging them all the way back up, you'll need minimum of 8KW/Hrs of storage capacity.
- W / 12VDC = 667 Ampere hours
- W / 24VDC = 333 Ampere hours
- W / 48VDC = 167 Ampere hours
So if you're able to set up a 48V solar system, you'd need 8 Trojan T-105 batteries hooked in series at a cost of $105 each plus cables and lugs, and you're looking at $1,000 just for your storage. And solar power is running about $5 a watt, so an additional $5,000 for the solar panels.
It can be done, but it's going to be expensive.