Hi Matrix,
yes, it could be used as generator. I have tried to use a car starter motor as generator. There are some starters with PM 6 or 8 pole stator and assembled gear box (Mercedes Benz, Toyota, etc.). But, car starters are not designedas for a long time running. There are not ball bearings, so, You will have a problem with lubrication and high friction . I am working with car starter now, but it will be another way to use it. I will rewind rotor and it will be 3 phase 8 pole AC brusheless generator .A colletor will be removed. It means that rotor will be as a shaft for PM stator. Stator will be spinning aroud a rotor. But it will take a lot of mechanical jobs.
Regards
Vigis & WIND KIDS