Not a lot of details to work on but yes that would be possible. You don't say whether this is single phase or 3 phase. Neither do you say whether he has the water available to produce the 15kW. I can't imagine trying to feed the whole output to batteries at 300A. If so then it will need a monster transformer and if it is single phase you may not get a high % of the full 15kW. If you want a decent battery charger than starting with 3 phase is a better proposition.
Not sure what you mean about the transformer being over rated, it depends on the charge you want to get into the battery.
To reach charge voltage the transformer will need a secondary voltage in excess of 38v. How much more you need depends on many factors. I personally would use a choke filter after the rectifier to increase the conduction angle and that would require nearer 70v ac but few do things this way.
I can't offer you detailed advice with so little information.
Flux