there's like 4 orders of magnitude difference, those caps are supporting a current greater than what the battery can handle for as much as a tenth of a second.
your desulphator is probably pushing single digit amps at a lot of volts for a few micro seconds.
one theory on how they work(if they do or not) is the sulphate that is not electrically conductive (gamma, as opposed to the alpha and beta forms of the crystal) can be recharged by sending current into it via the capacitive coupling between the crystal and the plate.
btw, and i've said this before elsewhere, the most efficient place to put those capacitors is on the 80-120 volt dc bus after the boost converters inside the audio amp, as the boost converter's losses follow the square of the current, if the caps can average out the bass beat it will require significantly less volume of capacitance, as the cap can discharge proportionally farther than can the 12 volt side.