If the magnets are properly stuck on with reliable adhesive then the vinyl ester should provide weather protection.
If you are relying on it for holding the magnets then I would suggest a band of some sort. If you can't get stainless then thin mild steel wouldn't have much effect on the flux, there is bound to be some loss but I can't see it being an issue with something less than 1/16" thick.
Cleaning the discs carefully with abrasive or grit blasting or something makes very good sense if you are relying on bonding the magnets to use without a band. if you use a band then just removing active rust and grease is probably adequate.
I think vinyl ester works better than polyester so for weather protection it should be perfectly adequate but I wouldn't consider it a structural glue. The better epoxies should do the job without banding.
I think even vinyl ester should be ok with a fiberglass banding round the magnets as long as you key the resin mass to stop it sliding with some holes, roll pins or screws.
Just a resin block with the magnets right up to the edge of the discs and no banding requires a structural adhesive to hold the magnets or epoxy potting to be sure, although I think the issue is much less than many think. nearly all magnet coming off issues are after some other failure such as a stator rub with heat demagnetising them.
The magnetic forces are nearly enough to hold things under normal conditions and you are mainly using the resin block to keep things from sliding. Demagnetised magnets would be really much more demanding to hold on.
Flux