Two of the major failure modes of car batteries are:
- Sulfation (high resistance, reduced capacity) and
- High self-discharge from flaked-off plate material piling up at the bottom of the cells.
If your batteries are free you can get around partial sulfation (if it hasn't broken up or clogged the plates too badly) by just having a lot more batteries. B-)
High self-discharge will cause the battery to discharge overnight, making it useless for storage. But you can cure that by rinsing it out and installing fresh electrolyte. (Ick!) You end up with less than the original capacity, of course, but it's a working cell again.
Some other failure modes are more terminal - like a dendrite-shorted cell, heavy sulfation, or broken-up plates. But those will show up as a battery that won't take a charge, or shows an extremely high charging voltage.
Car batteries, though, are NOT designed for deep-cycling and will break down rapidly (like in a few months) if you use them for that sort of application. If you don't mind bringing home a new set of old batteries every couple months you'll do OK - at least until your area starts charging for disposal of old batteries. B-(