You don't say what you are doing with the 65v dc, I assume you are not using it direct, are you charging a battery or something.
If you are charging batteries then capacitors will do nothing, if you are running a direct load then capacitors will mess up your voltage.
Decent press fit or stud mounted diodes will produce less heat than a isolated base dedicated bridge. You will do better with 3 individual diodes on each heat sink than a potted bridge on a bigger sink.
With decent stud diodes you can run the heatsinks up to about 60 deg C ( too hot to hold) With potted bridges you may have to hold the sink temperature down to keep the junctions within their thermal limits.
Sink fins need to be vertical for air cooling, good size fins are better than a larger area with small fins.
Fans are fine short term but usually end in disaster long term, they always fail, in this case I certainly wouldn't consider one.
Your voltage is too high for schottky to gain you much,I haven't seen any that I would run at 65v (150v piv with battery). The volt drop on the higher volt ones tends to be higher anyway.
For air cooling to work you need the sinks at a reasonable temperature, you will need monster sinks if you want them cold. I hate those potted bridges.
Flux