I've though of using propane. Much cheaper than (other) liquid refrigerants. Liquid at reasonable pressure. Suitable containers and plumbing are easy to come by.
Site it far from the house, though. You'd need several pounds of it, so a leak would make a BIG flame and possibly a substantial explosion. B-b
Now that I think of it, carbon dioxide ought to do the job, also. A leak would mostly ice up the equipment.
Or just spring a few hundred for a refrigerant charge.